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Abstract
Three perylene tetracarboxylic diimide (PDI) compounds, namely, N,N'- di(2-N'',N''-dimethylamino)ethylperylene-3,4:9,10-tetracarboxylic diimide (1), N,N'-di(2-N'',N''-dimethylamino)propylperylene-3,4:9,10-tetracarboxylic diimide (2), and N,N'- dicyclohexyl-1,7-pyrrolidinylperylene-3,4:9,10-tetracarboxylic diimide (3), have been designed and prepared. Their photophysical properties in room-temperature ionic liquid (RTILs) were studied by steady-state absorption and emission spectra and fluorescence lifetime measurements. The intramolecular photoinduced electron transfer from dimethylamine to PDI in 1 and 2 has been efficiently hindered because of the solvation of RTILs. A two-conformation mechanism for the PET in 1 and 2 is proposed, which explains the results of the fluorescence lifetime measurements well. The solvation of RTILs to 3 resembled that of a normal polar organic solvent with polarity larger than that of DMF.
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