Abstract
The key intermediate in the synthesis of ester, carbonate and acetal rotaxanes is a new supramolecular anionic template, which consists of a “wheeled” phenolate that acts as a supramolecular nucleophile in a threading reaction, with up to 81 % yield. One result of this synthetic concept is the shown rotaxane that contains probably the shortest axle centre part ever incorporated in a rotaxane.
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