High-Throughput Transformation of Colloidal Polymer Spheres to Discs Simply via Magnetic Stirring of Their Dispersions

Abstract

In this article, we have successfully demonstrated the high-throughput production of colloidal discs via magnetic stirring of aqueous dispersions of monodisperse, sulfate-stabilized polystyrene (PS) spheres in the presence of a good organic solvent. The organic solvent could be water-miscible, such as tetrahydrofuran, or water-immiscible, such as chloroform. Water-immiscible organic solvents were mixed into aqueous dispersions of PS spheres in the presence of sodium dodecyl sulfate. The geometry of the resulting discs could be easily adjusted by the magnetic stirring time and speed, the stirring bar weight, and the amount of organic solvent. Our strategy is simple, scalable, and hardly dependent on the nature of the organic solvent and the PS sphere diameter; PS spheres with diameters ranging from 200 nm to 5 μm were deformed into discs with almost 100% yield. When organic solutions of fluorescent dyes and nanoparticles were used instead of pure organic solvents for PS sphere liquefaction, fluorescent discs were obtained, underlining the effective, efficient encapsulation of the fluorescent substance in the discs.