Abstract
Diamond-like carbon (DLC) coatings show a low coefficient of friction (COF) and high wear resistance against aluminum at elevated temperatures, yet they exhibit a high running-in COF (μ R ) prior to reaching a low and stable steady-state COF (μ s ). This study shows that incorporating titanium (Ti) atoms into the DLC structure would reduce the μ R . During pin-on-disk tests conducted on Ti incorporating hydrogenated-DLC (Ti-H-DLC) with 6.2 at.% Ti subjected to dry sliding against 319 Al (Al-6.5% Si), μ s values decreased from 0.27 at 25 °C to 0.11 at 200 °C. The specific wear rate of Ti-H-DLC decreased from 2.44 × 10 −5 mm 3 /Nm at 25 °C to 0.71 × 10 −5 m 3 /Nm at 200 °C. A typical DLC with 40 at.% H (H-DLC) tested at 200 °C showed a low μ s of 0.08 and a wear rate of 1.11 × 10 −5 mm 3 /Nm. However, at 200 °C, Ti-H-DLC showed a lower μ R of 0.16 compared to μ R = 0.78 of H-DLC, and the duration of the running-in period for Ti-H-DLC, t R = 3 revolutions, was shorter than H-DLC with t R of 200 revolutions. Comparisons made with other DLCs, including, NH-DLC, W-DLC, ta-C, and Si-O-H-DLC, in addition to H-DLC, all tested using the same method, revealed that, in the temperature range of 100–250 °C, Ti-H-DLC showed a better running-in behavior making Ti-H-DLC a suitable tool coating for manufacturing processes where high-temperature running-in sliding friction is important, including warm forming and (single-point) turning of aluminum alloys . • High-temperature tribological behavior of Ti-H-DLC against 319 Al was studied. • Low running-in COF and short running-in duration were recorded at 100 and 200 °C. • Compared to other DLC coatings, the lowest μ R and t R were obtained using Ti-H-DLC. • Ti-H-DLC tool coatings are useful for Al warm forming, machining operations ~200 °C.
Published Version
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