Abstract

The main aim of this work is to investigate the effects of combinative Ce and Zr additions (0.3 wt% Ce + 0.16 wt% Zr; 0.3 wt% Ce + 0.27 wt% Zr and 0.3 wt% Ce + 0.36 wt% Zr) on the microstructure and mechanical properties in cast Al–Si–Cu–Mg alloy. The microstructures features were investigated by optical microscope, scanning electron microscope and hardness measurements. The microstructural analysis has shown that the increase of Ce and Zr contents increases the volume fraction of intermetallics formed during the solidification leading to grain refinement and changes in silicon morphology of the as-cast microstructure. The intermetallics formed do not dissolve during the solution heating treatment (T6). The mechanical behavior at room and high temperatures (175, 210, 245 and 275 °C) was determined from uniaxial tensile tests. The high thermal stability of Al–Si–Cu–La–Ce and Al–Si–Zr–Ti–Mg phases found in microstructure, in particular for the alloy containing 0.3 wt% Ce + 0.27 wt% Zr, is responsible for the increase to 6.7% and 5.1% the ultimate strength at 210 °C and 275 °C respectively, compared with the standard alloy.

Highlights

  • The increasing requirement to improve fuel economy triggered by concerns about global warming and energy usage has a significant influence on the choice of materials [1], leading to the need for lighter alloys accompanied with enhanced mechanical properties [2]

  • Recent studies on aluminum alloys modified with the minor Zr additions [3, 5, 16, 20,21,22] demonstrated a significant enhancement in high-temperature mechanical properties due to the increase of volume fraction of highstable intermetallic phases formed in the microstructure

  • The grain refinement due to zirconium in cast alloys can be explained by the reaction L + Al3Zr = α(Al) according to [32]

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Summary

Introduction

The increasing requirement to improve fuel economy triggered by concerns about global warming and energy usage has a significant influence on the choice of materials [1], leading to the need for lighter alloys accompanied with enhanced mechanical properties [2]. It is well known that cast aluminum alloys have operational limitations when used at temperatures up to 150 °C due to the recognizable low thermal stability of Al2Cu and Mg2Si precipitates. In this context, it is clear that the main challenge for aluminum alloys is to keep their strength at temperatures above 200 °C [4, 5]. Recent studies on aluminum alloys modified with the minor Zr additions [3, 5, 16, 20,21,22] demonstrated a significant enhancement in high-temperature mechanical properties due to the increase of volume fraction of highstable intermetallic phases formed in the microstructure

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