Abstract

Fluorescent polymer hydrogels (FPHs) with tunable luminous features have attracted immense interest. Nevertheless, until now, the development of most FPHs had been hindered by their poor mechanical properties and limited application range. This study presents a novel strategy to fabricate high-strength, multi-application cellulosic fluorescent hydrogels using polyvinyl alcohol (PVA) and fluorescent nanocellulose (containing pyrene tetracarboxylic acid) through a salting-out process. Such strategy enables cellulosic hydrogels with high tensile strength and toughness (26.45 MPa and 201.27 MJ/m3), compressive strength (165.58 MPa), dual-responsive fluorescence (acid/base and temperature), and multiple applications. Specifically, cellulosic hydrogels exhibit fluorescence switching through the utilization of lanthanide metals (Eu3+/Tb3+), acid/base, and temperature, owing to the presence of perylene tetracarboxylic acid as a fluorescent moiety with an aggregation-caused quenching (ACQ) effect. Based on this, the resulting hydrogels were utilized in rewritable display systems, temperature monitoring, and encrypted QR codes. This study envisions opening new possibilities for the development of high-strength fluorescent hydrogels with multiple applications.

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