Abstract
The ν 1 + ν 3 band of ozone (O 3) near 2110 cm −1 has been measured and analyzed using a Watson-type Hamiltonian including all seven sextic centrifugal distortion terms. Two weak perturbations have been found between K = n of ν 1 + ν 3 and K = n + 3 of 2 ν 3. Those perturbations locate the band center for 2 ν 3 at about 2058 cm −1. Aside from those perturbations the interactions of ν 1 + ν 3 with 2 ν 1 and 2 ν 3 have not been taken into account in the analysis. Effective band constants and an atlas listing line wavenumbers and assignments are given.
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