Abstract

The separation of diastereomeric C 8C 20 alkanes using mesogenic stationary phases has been studied. A comparison of the retentions of the diastereomers on mesogenic and non-mesogenic phases showed the effect of the mesophase diastereoselectivity. Examples of the separation of some diastereomeric C 9C 10 alkanes indicated that liquid crystals may be useful stationary phases in the capillary gas chromatographic separation of diastereomeric compounds.

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