Abstract

High-resolution gas chromatography and high-performance liquid chromatography (HPLC) of organoarsenic compounds is reported. Thermogravimetric analysis indicates that analyte decomposition may occur in injection and detection interfaces, thus careful temperature'control is needed. Specific element detection for arsenic and carbon was by microwave induced plasma spectroscopy. HPLC was optimized on phenylbonded silica with hexane-dichloromethane mobile phase. Eluate integrity was confirmed by d.c. argon plasma emission.

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