Abstract

To meet the requirements of high-power products (ex. electric scooters, hybrid electric vehicles, pure electric vehicles and robots), high-energy safe lithium-ion batteries need to be developed in the future. This research will focus on the microstructures and electrochemical properties of olivine-type LiFePO 4 cathode materials. The morphologies of LiFePO 4/C composite materials show spherical-type particles and have good carbon conductive networks. From the TEM bright field image and EELS mapping, the LiFePO 4/C powder shows continuous, dispersive nano-carbon network. These structures will improve electron transfer and lithium-ion diffusion for LiFePO 4 cathode materials, and increase their conductivity from 10 −9 S cm −1 to 10 −3 S cm −1. The electrochemical properties of LiFePO 4/C cathode material in this work demonstrated high rate capability (≥12 C) and long cycle life (≥700 cycles at a 3 C discharge rate).

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