High-Potential Cathodes with Nitrogen Active Centres for Quasi-Solid Proton-Ion Batteries.

Abstract

Although proton-ion batteries have received considerable attention owing to their reliability, safety, toxin-free nature, and low cost, their development remains in the early stages because of lacking proper electrolytes and cathodes for facilitating a high output voltage and stable cycle performance. We present a novel cathode based on active nitrogen centre, which provides a flat discharge plateau at 1 V with a capacity of 115 mAh g-1 and excellent stability. Moreover, a quasi-solid electrolyte was developed to overcome the issue of corrosion, broaden the potential window of the electrolyte, and prevent the active material from dissolving. While using the unique as-developed electrolyte, the newly designed cathode retained 89.67 % of its original capacity after 2000 cycles. Finally, we demonstrated the excellent cycle performance of the as-developed metal-free, flexible, soft-packed battery. Notably, even when a portion of the battery was cut off, it continued to function normally.