High-performance multifunctional polyvinyl alcohol/starch based active packaging films compatibilized with bioinspired polydopamine nanoparticles

Abstract

Bioinspired polydopamine (PDA) nanoparticles were synthesized and explored as functional compatibilizers in polyvinyl alcohol/starch (PVA/ST) matrix to develop high-performance multifunctional packaging film. The effect of the addition of PDA on the microstructural, mechanical, thermal, water vapor barrier, ultraviolet (UV)/high-energy blue light (HEBL) blocking, thermal insulating and antioxidant properties of PVA/ST composite films was fully investigated. Results demonstrated that the added PDA nanoparticles were evenly dispersed in the PVA/ST matrix, providing compact and dense nanocomposite films due to their compatibilization effect. Compared with virgin PVA/ST film, the resulting PVA/ST/PDA nanocomposite films exhibited greatly improved tensile strength, toughness, thermal stability, and water vapor barrier ability. Furthermore, the presence of PDA endowed PVA/ST composite film with excellent UV/HEBL blocking, thermal insulating as well as antioxidant functions. Thus, such high-performance multifunctional nanocomposite films hold the potential of protecting food quality against photothermal oxidative deterioration and extend food shelf life.