Abstract

Aluminum oxynitride (AlON) powders were synthesized by the carbothermal reduction and nitridation process using commercial γ-Al2O3 and carbon black powders as starting materials. And AlON transparent ceramics were fabricated by pressureless sintering under nitrogen atmosphere. The effects of ball milling time on morphology and particle size distribution of the AlON powders, as well as the microstructure and optical property of AlON transparent ceramics were investigated. It is found that single-phase AlON powder was obtained by calcining the γ-Al2O3/C mixture at 1550°C for 1h and a following heat treatment at 1750°C for 2h. The AlON powder ball milled for 24h showed smaller particles and narrower particle size distribution compared with the 12h one, which was benefit for the improvement of optical property of AlON transparent ceramics. With the sintering aids of 0.25wt% MgO and 0.04wt% Y2O3, highly transparent AlON ceramics with in-line transmittance above 80% from visible to infrared range were obtained through pressureless sintering at 1850°C for 6h.

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