Abstract
AbstractAn asymmetric [3+2] cycloaddition of racemic vinyl epoxides with N‐benzothiazolimines has been presented under Pd‐catalysis. This transformation provides rapid access to highly functionalized oxazolidine scaffolds in generally good yields along with high stereoselectivities (up to 99% ee, 8.5 : 1 d.r.) under mild conditions. The use of chiral BINAP ligand enabled this asymmetric transformation with a broad substrate tolerance.
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