Abstract
This study focused on evaluating the catalytic properties for the reverse water gas shift reaction (RWGS: CO2 + H2 → CO + H2O ΔH 0 = 42.1 kJ mol-1) in the presence of hydrogen sulfide (H2S) over a Fe/CeO2 catalyst, commercial Cu-Zn catalyst for the WGS reaction (MDC-7), and Co-Mo catalyst for hydrocarbon desulfurization. The Fe/CeO2 catalyst exhibited a relatively high catalytic activity to RWGS, compared to the commercial MDC-7 and Co-Mo catalysts. In addition, the Fe/CeO2 catalyst showed stable performance in the RWGS environment that contained high concentrations of H2S. The role of co-feeding H2S was investigated over the Fe/CeO2 catalyst by the temperature programmed reaction (TPR) of CO2 and H2 in the presence of H2S. The result of TPR indicated that the co-feeding H2S might enhance RWGS performance due to H2S acting as the hydrogen source to reduce CO2.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
