Highly Sensitive, Multiparametric Thermal History Phosphor Based on An Eu(BTC) Architecture

Abstract

AbstractThe capacity to discern the highest temperature that an object is subjected to is a crucial diagnostic tool. Consequently, the pursuit of materials that enable the luminescence‐based investigation of the thermal history of an object with high sensitivity is of great importance from the functional applications standpoint. This study aims to present a multiparametric thermal history phosphor based on the luminescent coordination polymer [Eu(BTC)(H2O)6] [Eu(BTC)‐1, where H3BTC = 1,3,5‐benzenetricarboxylic acid]. The progressive dehydration that Eu(BTC)‐1 undergoes as a function of temperature increase in the 343–425 K range results in significant alterations in both the shape of the Eu3+ ions emission spectrum and the depopulation kinetics of their 5D0 level. Based on this occurrence, a thermal history phosphor with an unprecedentedly high relative sensitivity of 11.3% K−1 in ratiometric mode, and 1.8% K−1 in lifetime‐based mode, is developed. The outcomes of this research are expected to stimulate a wide interest in the exploitation of (porous) coordination polymer‐type materials for the development of thermal history phosphors.