Highly Sensitive, Breathable, and Flexible Pressure Sensor Based on Electrospun Membrane with Assistance of AgNW/TPU as Composite Dielectric Layer

Jie Wang,Yaoyuan Lou,Mingwei Zhou,Xiuyan Li,Qing Sun,Bin Wang

doi:10.3390/s20092459

Jie Wang, Yaoyuan Lou + Show 4 more

Open Access

https://doi.org/10.3390/s20092459

Copy DOI

Abstract

Pressure sensors have been widely used in electronic wearable devices and medical devices to detect tiny physical movements and mechanical deformation. However, it remains a challenge to fabricate desirable, comfortable wearing, and highly sensitive as well as fast responsive sensors to capture human body physiological signs. Here, a new capacitive flexible pressure sensor that is likely to solve this problem was constructed using thermoplastic polyurethane elastomer rubber (TPU) electrospinning nanofiber membranes as a stretchable substrate with the incorporation of silver nanowires (AgNWs) to build a composite dielectric layer. In addition, carbon nanotubes (CNTs) were painted on the TPU membranes as flexible electrodes by screen printing to maintain the flexibility and breathability of the sensors. The flexible pressure sensor could detect tiny body signs; fairly small physical presses and mechanical deformation based on the variation in capacitance due to the synergistic effects of microstructure and easily altered composite permittivity of AgNW/TPU composite dielectric layers. The resultant sensors exhibited high sensitivity (7.24 kPa−1 within the range of 9.0 × 10−3 ~ 0.98 kPa), low detection limit (9.24 Pa), and remarkable breathability as well as fast responsiveness (<55 ms). Moreover, both continuously pressing/releasing cycle over 1000 s and bending over 1000 times did not impair the sensitivity, stability, and durability of this flexible pressure sensor. This proposed strategy combining the elastomer nanofiber membrane and AgNW dopant demonstrates a cost-effective and scalable fabrication of capacitive pressure sensors as a promising application in electronic skins and wearable devices.

Highlights

Pressure sensors that transform external stimulation to electronic signals has received extensive attention in the past few years, with typical sensing methods such as transistor pressure sensors [1], piezoelectric pressure sensors [2,3,4,5], capacitive pressure sensors [6,7], piezoresistive pressure sensors [8,9,10,11] and triboelectric pressure sensors [12,13]
In our previous research [35], we reported a breathable capacitive pressure sensor with good sensitivity of 4.2 kPa−1 based on a sandwich structure, which was composed of two AgNW/poly(vinylidene fluoride) (PVDF) nanofiber membrane electrodes and a thermoplastic polyurethane elastomer (TPU) nanofiber membrane dielectric layer
thermoplastic polyurethane elastomer rubber (TPU) electrospinning nanofiber membranes (ENMs) and AgNW/TPU ENMs were studied in terms of their morphology, composition, Instrument, Yantai, China) was used to test the breathability of the nanofiber membranes

Summary

Introduction

Pressure sensors that transform external stimulation to electronic signals has received extensive attention in the past few years, with typical sensing methods such as transistor pressure sensors [1], piezoelectric pressure sensors [2,3,4,5], capacitive pressure sensors [6,7], piezoresistive pressure sensors [8,9,10,11] and triboelectric pressure sensors [12,13]. Capacitive pressure sensors with high sensitivity and good flexibility have been investigated, the current performances of on-skin sensors show that it is difficult to satisfy the needs of accurate and continuous physiological detection over a long period of time [23]. To address this challenge, constructing various microstructures onto a pressure sensing layer was first thought of by researchers such as pyramids, lotus leaf, and gradient wrinkles [24,25,26].

Methods

Results

Conclusion