Highly selective recovery of rare earth elements from mining wastewater using phyto-synthesized biochar dispersed iron nanoparticles

Abstract

Recovery of rare earth elements (REEs) from secondary sources such as mining wastewater has attracted much recent attention due to the rising global demand for REEs and the need to environmentally protect potentially contaminated mine sites. One significant issue it that most adsorbents proposed for removal and/or recovery of REEs are not generally selective for REEs. In this study, biochar dispersed iron nanoparticles synthesized using a plant extract (BC-FeNPs) were successfully used for the selective recovery of REEs from mining wastewater, where the Kd values were Nd(III) (918 mL∙g−1), Eu(III) (1253 mL∙g−1), Tb(III) (1119 mL∙g−1), Dy(III) (1032 mL∙g−1), Lu(III) (1898 mL∙g−1), compared to only 23.9 mL∙g−1 for Zn(II). The maximum adsorption efficiency of REEs for the composite was higher than the constituent parts being 88.4 % for BC-FeNPs, but only 8.72 % for biochar and 82.4 % for FeNPs, respectively. FTIR, XPS and Zeta potential analysis suggested that the observed selective adsorption of REEs, involved interactions of REEs with O and N, as well as ion-exchange with H+ from the biochar and capping layer, as well as electrostatic interactions. The desorption efficiency of bound REEs from BC-FeNPs was > 85 % when using acetic acid, and was attributed to efficient competitive ion exchange. Pearson correlation analysis further demonstrated that the adsorption mechanism included ion complexation, ion exchange and electrostatic adsorption, while the desorption mechanism was mainly via ion exchange. Overall, BC-FeNPs has significant potential to practically recover REEs from mining wastewater having demonstrated excellent reusability after five adsorption–desorption cycles.