Highly selective electrochemical sensing based on electropolymerized ion imprinted polyaniline (IIPANI) on a bismuth modified carbon paste electrode (CPE-Bi) for monitoring Nickel(ii) in river water.

Abstract

Electrochemical sensors based on ion-imprinting polymers have emerged as an effective analytical tool for heavy metal tracking. This study describes a simple and facile technique for manufacturing a highly selective and sensitive electrode using an ion imprinting polymer on a bismuth-modified carbon paste electrode. The developed sensor applied aniline as a functional monomer and was used for tracking Ni(ii) ions. The proposed sensor was thoroughly characterized by scanning electron microscopy, cyclic voltammetry, and differential pulse striping anodic voltammetry. The analytical evaluation showed that the proposed sensor has a linear dynamic range (R 2 = 0.999) for the Ni(ii) concentration range of 0.01 to 1 μM and a limit of detection value of 0.00482 μM. The proposed sensor showed excellent performance when tested for tracking Ni(ii) ions in the presence of interfering ions (Cd(ii), Co(ii), Cu(ii), and Zn(ii) ions) at a 1000-fold higher concentration. When the proposed sensor was tested for tracking Ni(ii) concentration in an actual river sample, our modified sensor showed similar results compared to the atomic absorption spectroscopy evaluation (p > 0.05, n = 3). In summary, our proposed sensor is promising for monitoring Ni(ii) ions in the aquatic environment.