Highly selective detection and removal of mercury ions in the aquatic environment based on magnetic ZIF-71 multifunctional composites with sufficient chlorine functional groups

Abstract

The development of both detection and removal technologies for heavy metal ions is of great importance. Most of the existing adsorbents that contain oxygen, nitrogen or sulfur functional groups can remove heavy metals, but achieving both selective detection and removal of a single metal ion is difficult because they bind to a wide range of heavy metal ions. Herein, we selected zeolite imidazolium hydrochloride framework-71 (ZIF-71) with sufficient chlorine functional groups to fabricate magnetic ZIF-71 multifunctional composites (M-ZIF-71). M-ZIF-71 had a large specific surface area, excellent water stability, and good magnetic properties, which made M-ZIF-71 conducive to the separation and recovery of adsorbents and the assembly of electrodes. M-ZIF-71 exhibited high selectivity, wide linear range (1–500 μg/L), and low detection limit (0.32 μg/L) for electrochemical detection of mercury ions (Hg2+). Meanwhile, M-ZIF-71 demonstrated rapid Hg2+ adsorption with a high capacity of 571.2 mg/g and excellent recyclability. The high selectivity for Hg2+ was attributed to the powerful affinity of highly electronegative chlorine and Hg2+. Moreover, XPS spectra demonstrated the interaction between chlorine and Hg2+. This work provides a new inspiration for applications in the targeted monitoring and removal of heavy metal pollution.