Abstract

ZnZrO/Mg-Si-ZSM-5 tandem catalysts enable CO2 hydrogenation to para-xylene (PX) with PX selectivity up to 28% and a proportion of PX in xylene up to 84%. SiO2 and MgO modification increases the PX selectivity by reducing the Brønsted acid sites and reducing the pore size of the zeolite.

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