Highly selective and stable mixed-potential type gas sensor based on stabilized zirconia and Cd2V2O7 sensing electrode for NH3 detection

Abstract

In this work, the highly selective and stable mixed potential type stabilized zirconia (YSZ) based gas sensor using Cd2V2O7 sensing electrode (SE) synthesized via simple coprecipitation method was fabricated and developed for effective detection of NH3 at 650 °C. The as-prepared Cd2V2O7 sensing material was characterized by X-ray diffraction (XRD), Raman spectrum, X-ray photoelectron spectroscopy (XPS) and Field-emission scanning electron microscopy (FESEM). The results of gas sensing measurement indicated that the sensor attached with Cd2V2O7- SE displayed the response value of −68 mV and rapid response rate of 5 s to 100 ppm NH3 at 650 °C. The present device also exhibited the low detection limit of 1 ppm and the piecewise sensitivities of −6 and −66 mV/decade to NH3 in the concentration ranges of 1–10 ppm and 10–200 ppm, respectively. Moreover, the fabricated sensor showed good reproducibility, excellent selectivity, stability to oxygen concentration, relative humidity and 30 days continuous aging of high temperature at 650 °C. And the complex impedance and polarization curves were performed to explain the selectivity and verify the sensing mechanism involving mixed potential model.