Abstract
Abstract Extraordinarily ruffled acetato[5,10,15,20-tetra(tert-butyl)porphinato]manganese(III) has been prepared. The 1H NMR spectra have revealed that the inversion barrier of the porphyrin ring exceeds 66 kJ mol−1 and that the spin densities are quite different between the diastereotopic β-carbon atoms.
Published Version
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