Abstract
Abstract Reaction of the cyclic carbonates of acyclic vinyl diols with RCu(CN)Li· BF 3 , RCu(CN)MgBr·BF 3 , or RMgBr·CuI (cat) in THF at −78 °C proceeded in S N 2′ fashion and resulted in the formation of alkylated ( E )-allylic alcohols with remarkably high diastereoselectivity. This reaction represents an efficient 1, 3-chirality transfer method.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
