Highly porous cellulosic nanocomposite membranes with enhanced performance for forward osmosis desalination

Synthesis and characterization of flat-sheet thin film composite forward osmosis membranes

Hybrid membrane system for desalination and wastewater treatment : Integrating forward osmosis and low pressure reverse osmosis

In order to ensure long-term sustainability of the reservoir, the gas industry in Qatar is faced with the challenge of reducing the volume of produced and process water (PPW) sent to disposal wells by 50% [1-3]. Recently, Qatargas initiated a project to recycle process water and thus, reduce disposal volumes using commercial advanced water treatment technologies [4]. One emerging technology, “osmotic concentration” (OC) has been identified that offers a low-energy alternative to conventional thermal or membrane volume reduction methods. Osmotic concentration is a membrane filtration process that mimics first step in a forward osmosis (FO) system. It requires a high salinity draw solution (DS) which passes on one side of a semi-permeable FO membrane while the feed passes on the other side. Water from the feed is drawn through the membrane, via natural osmosis, reducing the feed volume and increasing the volume of the draw solution. This paper summarizes the results of bench-scale volume reduction tests wit...

A novel analysis of reverse draw and feed solute fluxes in forward osmosis membrane process

This study aimed to concentrate and recover resources from municipal wastewater with a novel forward osmosis (FO) system. The FO system used synthetic seawater as the draw solution (DS) to extract water from the feed solution (FS) (synthetic raw municipal wastewater). Because ammonium passed through the FO membrane from the FS to the DS, we cultivated an algal strain (Chlorella vulgaris) in the DS to remove and recover ammonium. For three consecutive FO cycles, the algal FO system removed 35.4% of the ammonium from the DS, increased the concentrations of COD and in the FS by 43.0%, and achieved a water flux of 11.59±0.49Lm-2 hr-1 . Throughout the FO cycles, the algal biomass concentration of the DS stayed at 606±29mgCOD/L due to simultaneous algal growth and DS dilution. This FO process may be feasible to implement for full-scale applications to concentrate wastewater and recover resources. PRACTITIONER POINTS: A novel forward osmosis (FO) system with an algal draw solution (DS) concentrated municipal wastewater and recovered resources (ammonium). Ammonium but not organic matter or phosphate diffused across the FO membrane from the feed solution (FS) to the DS. The algal FO system increased COD/phosphate concentration in the FS by 43.0% and removed 35.4% of ammonium from the DS. The water fluxes in the algal FO system and the control were 11.59 and 12.02Lm-2 hr-1 , respectively. The novel algal FO process has the potential to improve full-scale efficiency by concentrating municipal wastewater and recovering nutrients.

Rejection of nutrients contained in an anaerobic digestion effluent using a forward osmosis membrane

A new class of draw solutions for minimizing reverse salt flux to improve forward osmosis desalination

Fouling of cellulose triacetate(CTA) forward osmosis(FO) membranes by natural organic matter(NOM) was studied by means of a cross-flow flat-sheet forward osmosis membrane system. The NOM solution was employed as the feed solution(FS), and a sodium chloride solution(3 mol/L) was used for the draw solution(DS). The process was conducted at various temperatures and cross-flow velocities. The flux decline was investigated with 3 h forward osmosis operation. The substances absorbed on the membranes were cleaned by ultrasonic oscillation of the fouled membranes and were characterized by methodologies including fluorescence excitation-emission matrices (EEMs) and liquid chromatography with an organic carbon detector(LC-OCD), and the variations of membrane properties were also investigated by Fourier transform infrared spectrometer(FTIR) and a contact angle meter. It was noted that the rejection efficiency of NOM is remarkable and that ultrasonic oscillation is an effective method to extract the NOM fouled on the CTA membranes after FO process. A higher cross-flow velocity and lower temperature benefit the anti-fouling capacity of the membrane significantly. Although humic substances accounted for the majority of the NOM, aromatic proteins and amino acids were the main fouling components on the membranes, with symbolic FTIR peaks at 2355, 1408 and 873 cm−1. The present surface foulant made the membranes becoming more hydrophilic, as demonstrated by a significant decrease in contact angle(ranging from 20% to 46%) under all the operation conditions.

Assessing the major factors affecting the performances of forward osmosis and its implications on the desalination process

The present work aims to study forward osmosis process using different kinds of draw solutions and membranes. Three types of draw solutions (sodium chloride, sodium formate, and sodium acetate) were used in forward osmosis process to evaluate their effectiveness with respect to water flux and reverse salt flux. Experiments conducted in a laboratory-scale forward osmosis (FO) unit in cross flow flat sheet membrane cell. Three types of membranes (Thin film composite (TFC), Cellulose acetate (CA), and Cellulose triacetate (CTA)) were used to determine the water flux under osmotic pressure as a driving force. The effect of temperature, draw solution concentration, feed and draw solution flow rate, and membrane types, were studied with respect to water flux. The results showed an increase in water flux with increasing feed temperature and draw solution concentrations In addition, the flux increased with increasing feed flow rate while the flux was inversely proportional with the draw solution flow rate. The results showed that reverse osmosis membranes (TFC and CA) are not suitable for using in FO process due to the relatively obtained low water flux when compared with the flux obtained by forward osmosis membrane (CTA). NaCl draw solution gave higher water flux than other draw solutions and at the same time, revealed higher reverse salt flux.

In this study, treated wastewater and Multi-Stage Flash (MSF) brine were integrated into the Forward Osmosis (FO) system using pressure stimuli-responsive Nanofiltration (PSRNF) membranes to dilute magnesium, calcium, and sulfate MSF plant brine reject. The deposition of magnesium sulfate and calcium sulfate in the heat exchanger is one of the main issues affecting the performance and efficiency of MSF thermal desalination plants. Reducing the concentration of the divalent ions can minimize scale formation and deposition to a level that allows the MSF plant to operate at high top brine temperature (TBT) and without scale problems. The PSRNF membranes were chosen in the FO process because of their high water permeability, rejection of divalent and monovalent ions, small structure parameter (S), and inexpensiveness compared to commercial FO membranes. Three PSRNF membranes were tested in the FO process with the feed solution facing the active membrane layer to avoid active layer delamination. Although the PSRNF membrane exhibited negligible water flux at 0 bar, it increased when a 2–4 bar was applied to the feed solution. The wastewater temperature was set at 25 °C while 40 °C was the brine operational temperature to mimic the field situation. A maximum average water flux of 39.5 L/m2h was recorded at 4 bar feed pressure when the PSRNF membrane was used for the brine dilution, achieving up to 42% divalent ions dilution at 0.02 kWh/m3 specific power consumption. The average water flux in the PRSNF membrane was 35% higher than that in the commercial TFC FO membrane. Notably, the PSRNF membrane is ten times cheaper than commercial FO membranes. Notably, the PSRNF membrane is ten times cheaper than commercial FO membranes, achieving substantial cost reductions and pioneering advancements in FO purification technology.

We tested the possibility of energy-saving water treatment methods by using a pump-less forward osmosis (FO) and low-pressure membrane (LPM) hybrid process (FO-LPM). In this pump-less FO-LPM, permeate migrates from the feed solution (FS) to the draw solution (DS) through the FO membrane by use of osmotic pressure differences. At the same time, within the closed DS tank, inner pressure increases as the DS volume increases. By using the DS tank’s internal pressure, the LPM process works to re-concentrate the diluted DS, maintaining the DS concentration and producing clean water. In this study, a polymer - polystyrene sulfonate (PSS) was used as a draw solute. Based on the results of each individual portion of the process, the optimal range of the PSS DS was determined. The performance of the pump-less FO-LPM process was lower than that of a single process; however, we observed that the hybrid process can be operated without a pump for regeneration of a diluted DS. This research highlights the feasibility and applicability of pump-less FO-LPM processes using a polymeric DS for water treatment. Additionally, it is suggested that this novel process offers a breakthrough in FO technology that is often limited by operation and management cost.

Characterization and membrane stability study for the switchable polarity solvent N,N-dimethylcyclohexylamine as a draw solute in forward osmosis

Evaluation of forward osmosis as a pretreatment process for multi stage flash seawater desalination

Influence of the process parameters on hollow fiber-forward osmosis membrane performances