Highly porous and conductive functional carbon fibers from electrospun phosphorus-containing lignin fibers

Abstract

Functional carbon fibers were prepared by carbonization of thermostabilized electrospun lignin-fibers at 500–900 °C followed by a high temperature thermal treatment at 1200–1600 °C. The effect of the preparation temperature on their surface chemistry, structural order, textural properties and electrochemical behavior has been stablished. Maximum porosity development is obtained at 900 °C. The addition of phosphoric acid in the electrospinning lignin solution shortens the stabilization time of the fibers, increases the carbonization yield, generates phosphorus functional groups (P content as high as 3% wt.) and increases the BET surface area of carbon fibers from 840 to 1143 m 2 g −1 . Interestingly, when phosphorus-containing carbon fibers are treated even at very high temperature, 1600 °C, most of the porosity is preserved (A BET = 822 m 2 g −1 ). XPS depth profile reveals the presence of reduced phosphorus in the core of carbonized fibers. XRD and TEM analysis make evident that the presence of phosphorus induces curvature of the graphitic layers, which seems to hinder the stacking of the graphene layers, explaining the preservation of microporosity after the thermal treatment at high temperature. However, Raman and XRD analyses point out that the presence of phosphorus does not affect the lateral growing of the crystallites. Thus, phosphorus preserves the porosity and allows the development of the electrical conductivity after the thermal treatments. Gravimetric capacitances of 79 F g −1 and capacitance retention of 63% at 68 A g −1 have been determined for phosphorus-containing carbon fibers prepared at 1200 °C. • Electrospinning of H 3 PO 4 lignin solution produced P-containing carbon fibers. • Experimental evidence about curvature of graphitic layers induced by P is reported. • P impedes the stacking of graphene layers while allowing their lateral growing. • P in carbon fibers core prevents from porosity shrinkage after heat treatment at 1600 °C. • Electrical conductivity and capacitance retention is promoted after heat treatment.