Highly photoactive novel NiS/BiOI nanocomposite photocatalyst towards efficient visible light organic pollutant degradation and carcinogenetic Cr (VI) reduction for environmental remediation

Abstract

Heterojunction engineering in catalyst structures is a promising approach for solving the main restriction of the narrow photoabsorption range and quick recombination of photogenerated charge carriers in the photocatalysts. Herein, a simple, eco-friendly, non-toxic, and novel Z-scheme heterojunction of nanoflower-like NiS/BiOI was systematically designed using the low-temperature solvothermal and precipitation methods. The physicochemical and photo-electrochemical properties of the as-synthesized nanomaterials were characterized using XRD, FESEM, FT-IR, XPS, BET, UV–vis, PL, and EIS. NiS/BiOI nanomaterials exhibited a wide photoabsorption range (200–1000 nm), a narrow bandgap energy (1.76 eV), a large surface area (35.82 m2 g-1), and a low charge carrier recombination rate because of the synergistic effects of the NiS and BiOI photocatalysts, which could be the basis for superior photocatalytic efficiency. Particularly, the optimal 40% NiS/BiOI nanocomposite exhibited better stability and efficiency than the pure NiS and BiOI. The maximum degradation efficiency of rhodamine B (RhB) was 99.8% after 200 min, tetracycline (TC) was 96.3% after 140 min, and the photoreduction of Cr(VI) was 92.8% after 180 min rather than the pure NiS and BiOI under visible light irradiation. The constant rate (k) of RhB was approximately 10 and 4, TC was 12 and 4, and Cr(VI) was 10 and 8 times that of pristine NiS and BiOI, respectively. Radical trapping experiments and Tauc plot analysis proposed the design of the plausible Z-scheme reaction mechanism between NiS and BiOI, which has a crucial role in the rate of transportation and separation of electron/hole pairs. This investigation provides a venue for the design of a photoactive NiS-based nanocomposite for environmental remediation.