Highly oriented as-grown beta-phase bismuth oxide for optical MEMS

Abstract

AbstractReactive sputtering of bismuth has been used to form highly oriented beta-phase Bi2O3 thin films at 120 °C. Notably, the films consist of nearly vertical ~ 50 nm diameter nano-filaments of highly aligned β phase pure bismuth oxide. The optical characteristics of the films include a direct optical bandgap of 3.95 eV at 300 K and nearly negligible optical absorption in the wavelength range from 500 to 3000 nm. Nanoindentation experiments show that the mechanical characteristics of the films include reduced modulus and hardness values of 90 and 4.5 GPa, respectively. As fabricated, the films exhibit tensile stress which in combination with a relatively high refractive index value in the range of 2.4–2.5 makes the realized Bi2O3 films structurally and optically suitable for fabrication of optical microelectromechanical (MEMS) devices with applications in the visible to mid-infrared wavelength region, such as MEMS-based Fabry–Pérot microspectrometers, which is demonstrated through simulations. Graphical Abstract