Highly luminescent Cit/CaF2: Ce3+, Tb3+ nanoparticles and detection of Cu2+ ions

Abstract

Terbium doped calcium fluoride (CaF2:Tb3+) and cerium co-doped CaF2:Tb3+ (CaF2:Ce3+, Tb3+) nanoparticles were synthesized by the hydrothermal method by using citric acid (Cit) as surfactant. The as-synthesized nanoparticles have good dispersibility in water to form an aqueous transparent dispersion at a concentration of 20 mg/mL. The nanoparticles have the CaF2-type cubic structures. Photoluminescence (PL) investigation showed that energy transfer can be occurred effectively from Ce3+ ions to Tb3+ ions in Cit/CaF2: Ce3+, Tb3+ nanoparticles. And the PL intensity of Cit/CaF2: Ce3+, Tb3+ nanoparticles is very strong at a low concentration of 1 mg/mL, which is 16-fold as high as that of Cit/CaF2: Tb3+ nanoparticles. The strong green emission from Cit/CaF2: Ce3+, Tb3+ nanoparticles can selectively be quenched by Cu2+ ions in comparison to other metal ions and its detection limit is 1.02 × 10−5 M in an aqueous solution. The PL quenching is reversible by the addition of ethylenediaminetetraacetic acid disodium salt (EDTA-2Na) with the recovery of almost 80% of the original PL. The results revealed that Cit/CaF2: Ce3+, Tb3+ nanoparticles could find a promising application for the detection of Cu2+ ions in an aqueous solution.