Abstract

Schon ein wenig Gold kann glücklich machen: Schon 0.01 Mol-% eines chiralen Goldphosphats genügen, um eine asymmetrische Transferhydrierung von Chinolinen hoch stereoselektiv zu steuern (bis 98 % ee). Die achiralen Liganden am Goldzentrum haben dabei einen beträchtlichen Einfluss auf die Effizienz des Katalysators.

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