Abstract
A prominent effect of the phenylcarbamoyl protecting group on the asymmetric dihydroxylation (AD) reaction was confirmed in both of the reactions of allyl N-phenylcarbamate with AD- mix-α and -β, bringing about excellent enantioselectivity (>99% ee) to give ( R)- and ( S)-glycerol 1-( N-phenylcarbamate) in quantitative yields, respectively.
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