Abstract
New tridentate enantiomerically pure heteroatom catalysts, containing hydroxyl, sulfinyl and amino groups, proved to be highly efficient in the enantioselective nitroaldol (Henry) reaction to give the desired adducts in very high yields (up to 90%) and with ees up to 98%. The influence of the stereogenic centres located on the sulfinyl sulfur atom and in the amine moiety is also discussed.
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