Abstract
The first enantioselective Friedel-Crafts alkylation of N,N-dialkylanilines with trans-β-nitrostyrene catalyzed by a homochiral metal-organic framework constructed from (R)-2,2'-dihydroxy-1,1'-binaphthyl-6,6'-dicarboxylic acid has been developed. The reaction proceeded in high yields (∼96%) with excellent enantioselectivities (∼98% ee).
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