Highly Electroconductive Nanopapers Based on Nanocellulose and Copper Nanowires: A New Generation of Flexible and Sustainable Electrical Materials.

Abstract

Nowadays, the development of sustainable high-performance functional nanomaterials is in the spotlight. In this work, we report the preparation of a new generation of flexible and high electroconductive nanopapers based on nanofibrillated cellulose (NFC) and copper nanowires (CuNWs). Homogeneous red brick color nanopapers (thickness 30.2-36.4 μm) were obtained by mixing different amounts of NFC aqueous suspensions and CuNWs (1, 5, 10, 20, and 50 wt %), followed by vacuum filtration and drying. scanning electron microscopy (SEM) and energy-dispersive X-ray spectroscopy (EDS) analysis confirmed the incorporation of the different amounts of CuNWs, and their uniform and random distribution. All of the nanomaterials displayed good mechanical properties, viz., Young's modulus = 2.62-4.72 GPa, tensile strength = 30.2-70.6 MPa, and elongation at break = 2.3-4.1% for the nanopapers with 50 and 1 wt % of CuNWs mass fraction, respectively. The electrical conductivity of these materials strongly depends on the CuNW content, attaining a value of 5.43 × 104 S·m-1 for the nanopaper with a higher mass fraction. This is one of the highest values reported so far for nanocellulose-based conductive materials. Therefore, these nanopapers can be seen as an excellent inexpensive and green alternative to the current electroconductive materials for applications in electronic devices, energy storage, or sensors.