Highly efficient water splitting by a dual-absorber tandem cell

Abstract

Photoelectrochemical water-splitting devices, which use solar energy to convert water into hydrogen and oxygen, have been investigated for decades. Multijunction designs are most efficient, as they can absorb enough solar energy and provide sufficient free energy for water cleavage. However, a balance exists between device complexity, cost and efficiency. Water splitters fabricated using triple-junction amorphous silicon1,2 or III–V3 semiconductors have demonstrated reasonable efficiencies, but at high cost and high device complexity. Simpler approaches using oxide-based semiconductors in a dual-absorber tandem approach4,5 have reported solar-to-hydrogen (STH) conversion efficiencies only up to 0.3% (ref. 4). Here, we present a device based on an oxide photoanode and a dye-sensitized solar cell, which performs unassisted water splitting with an efficiency of up to 3.1% STH. The design relies on carefully selected redox mediators for the dye-sensitized solar cell6,7 and surface passivation techniques8 and catalysts9 for the oxide-based photoanodes. A photoelectrochemical cell made from combining a dye sensitized solar cell with a semiconductor-oxide photoanode is demonstrated to perform water splitting with an efficiency of up to 3.1%. As the scheme uses relatively inexpensive materials and fabrication techniques it could provide a cost effective approach to hydrogen production.