Highly efficient removal of quinolones by using the easily reusable MOF derived-carbon

Abstract

As anthropogenic antibiotics, quinolones, e.g., ofloxacin have adverse impacts on ecological systems and human heaths. The removal of quinolones is of great importance, and adsorption techniques have been widely used to remove this hazardous contaminant. However, a robust and easy-operating adsorbent is still emergently required due to the complex chemical structure of quinolones. In this study, we successfully synthesized the promising metallic carbons (MCs) containing carbon nanotubes and cobalt nanoparticles by carbonizing Zn/Co-ZIF at 900 °C. Three different molar ratios of Co and Zn were applied to optimize the adsorption capacity on ofloxacin (OFL). Results showed MC with molar ratio of Co and Zn at 3:1 (Co-CNT/NPC3/1) achieved the maximal adsorption capacity to 118.3 mg g-1. Its adsorption performance was satisfied in the pH range from 5 to 9 and ionic strengths at 0.01 M. The main mechanisms for these adsorptions were identified as electrostatic attraction, metal coordination and π-π EDA. Removal efficiencies of quinolones higher than 68 mg g-1 indicated the strong feasibility of this adsorbent for wastewater treatments. The regeneration of Co-CNT/NPC3/1 at 600 °C allowed its at least 4-time reusability and its magnetic property enabled external magnets to recycle it from real environments.