Highly efficient Plutonium(IV) uptake from acidic feeds using four extraction chromatography resins containing diglycolamides and ionic liquid

Abstract

Quantitative recovery of plutonium from lean effluents is one of the most challenging tasks for separation scientists. Four extraction chromatography (XC) resins containing substituted diglycolamide ligands viz. N,N,N',N'-tetra-n-pentyl diglycolamide (TPDGA), N,N,N',N'-tetra-n-hexyl diglycolamide (THDGA), N,N,N',N'-tetra-n-octyl diglycolamide (TODGA) and N,N,N',N'-tetra-n-decyl diglycolamide (TDDGA) and a room temperature ionic liquid (RTIL) were tested for the extraction of plutonium (IV) from nitric acid feed solutions. The relative efficiency of uptake of the metal ion in the entire range of HNO3 studied was: TPDGA > THDGA > TODGA > TDDGA, which was opposite to the chain length of the attached alkyl groups. Also, for all the four XC resins the uptake of Pu(IV) was found to decrease with increasing nitric acid concentration in the lower acidity range followed by an increase thereafter. The uptake of Pu(IV) with all the four XC resins was fitted into different kinetic and isotherm models. It was found that all the four resins followed the pseudo-second order kinetic model and Langmuir monolayer adsorption model. Column studies with these XC resins using a loading solution containing 1.2g/L Pu(IV) in 3M HNO3 showed early breakthrough for the higher homolog DGA ligands as compared to the lower homologs. Effective elution of the loaded Pu(IV) from the column was done in about 5.5 column volumes using a solution containing 0.5M oxalic acid in 0.5M HNO3.