Highly efficient photocatalytic oxidative desulfurization of dibenzothiophene with sunlight irradiation using green catalyst of Ag@AgBr/Al-SBA-15 derived from natural halloysite

Abstract

In recent decades, highly efficient deep desulfurization processes have become very necessary to decrease environmental pollution due to sulfur emissions from fuels. Herein, an enhanced photocatalytic desulfurization of a model fuel was investigated under sunlight irradiation using H2O2 as the oxidant and Ag@AgBr loaded mesoporous silica Al-SBA-15 as a catalyst. In this study, the photocatalyst (Ag@AgBr/Al-SBA-15) was synthesized via a chemical deposition using halloysite clay as the silica–aluminum source and characterized by X-ray diffraction, N2 adsorption, scanning electron microscopy, transmission electron microscopy, and UV–Vis diffuse reflectance spectroscopy (UV–Vis DRS). The UV–Vis DRS results revealed that the light absorption expanded to the visible region (λ>400nm) for the various Ag@AgBr nanoparticles doped in the mesoporous Al-SBA-15 material. The 30% Ag@AgBr/Al-SBA-15 sample with a 30% Ag@AgBr doping exhibited enhanced photocatalytic activity and showed high stability even after four successive cycles. The results demonstrated that initial dibenzothiophene concentrations (500ppm) reached 98.66% removal with 50mg of the catalyst dosage, 1.0mL of H2O2, for 360min of sunlight irradiation at 70°C.