Abstract

Abstract The Pd(dba)2–2P(OCH2)3CEt (dba = dibenzylideneacetone) system exhibited highly efficient catalysis in the insertion of acetylenes into Si–Si bonds of hexamethyldisilane, octamethyltrisilane, poly[(disilanylene)phenylene] , poly[(disilanylene)ethylene], and poly(dimethylsilylene).

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