Highly Efficient Oxygen-Activated Self-Cleaning Membranes Prepared by Grafting a Metal-Organic Framework-Derived Catalyst.

Abstract

In this study, an efficient oxygen-activated self-cleaning membrane was successfully prepared by grafting a metal-organic framework-devised catalyst (CuNi-C) onto a membrane surface, resulting in enhanced filtration performance and self-cleaning capability based on oxygen activation under mild conditions. The pore features, surface roughness, and surface hydrophilicity of the prepared membrane were analyzed and used to determine the causes of the enhanced filtration performance; the results showed that an increase in the porosity and surface roughness enhanced the permeate flux, and enhanced adsorption capacity and surface hydrophobicity improved the membrane removal efficiency. The self-cleaning mechanism was elucidated by identifying the reactive oxygen species (ROS) and detecting catalytic element valences. The results revealed that zero-valent Cu embedded into the membrane surface effectively activated natural dissolved oxygen (DO) to generate ROS that degraded organic pollutants. In this study, catalytic oxidation with DO as the oxidant was successively integrated with membrane separation to prevent membrane fouling, providing a novel direction for the development of multifunctional membranes.