Highly efficient conversion of the nitroarenes to amines at the interface of a ternary hybrid containing silver nanoparticles doped reduced graphene oxide/ graphitic carbon nitride under visible light

Abstract

In this report, a ternary Ag-rGO/g-C3N4 hybrid was synthesized by a simple hydrothermal approach for the photocatalytic reduction of nitroarene compounds into their corresponding amines under visible light. Importantly, the present method did not require reducing agents, like hydrazine hydrate; instead methanol has been used as a source of electrons and protons for the photoreduction process. After grafting of Ag NPs, a significant enhancement in the efficiency of the rGO/g-C3N4 for the reduction of nitrobenzenes was observed. Under optimized experimental conditions, the conversion of nitrobenzene and yield of aniline were determined to be 99% and 98%, respectively under visible light illumination for 4 h. The nitrobenzene compounds bearing both electron donating and withdrawing groups were selectively converted into their corresponding aniline products without altering the functionality. The enhanced performance of the developed photocatalyst attributed to the effective separation of photoexcited electrons on the photocatalyst surface and their subsequent transfer for the reduction of nitrobenzene molecules.