Abstract
This paper discloses that inexpensive hydrobromic acid (HBr) is active and highly selective to the photo-oxidation of 5-hydroxymethylfurfural (HMF) to 2,5-diformylfuran (DFF) with dioxygen (O2) or even with water under visible light illumination, which can achieve the highest 89.1% DFF yield in DMSO at 80 °C under pure O2 atmosphere. More importantly, under bifunctional acid-photooxidation catalysis of HBr, fructose can be directly converted to DFF and its two-step cascade conversion in DMSO provides a far higher DFF yield (80.2%) than the one-step cascade conversion in MeCN (42.1%). The results of HMF photooxidation catalyzed by hydrohalic acids, free radical quenching tests and EPR spectrum support that the Br atom and superoxide (O2−˙) anion radicals generated by HBr photolysis in O2 are active species for the oxidation of HMF to DFF and their activities are adjusted by the reaction medium. This photo-synthetic protocol is very simple and practical, especially with low operating costs, showing a good industrial application prospect.
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