Abstract

AbstractA chloroform membrane system containing dibenzodiaza‐15‐crown‐4 was found to be a highly efficient and selective transport of Ag+ ions through a chloroform liquid membrane. In the presence of thiosulfate ion as a suitable ion stripping agent in the receiving phase, the amount of silver transported across the liquid membrane after 105 minis 95 ± 1.3%. The selectivity of Ag+transport from aqueous solutions containing Tl+, Pb2+, Cd2+, Ni2+, Co2+, K+, Ca2+, Sr2+, Hg2+, Zn2+, Cu2+was investigated. The interfering effect of Cu2+ ions was drastically diminished in the presence of EDTA as a proper masking agent in the source phase.

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