Highly efficient and reversible low-concentration SO2 absorption in flue gas using novel phosphonium-based deep eutectic solvents with different substituents

Abstract

Four hydrogen bond acceptors (HBAs) with different carbon chain length substituents, including methyl-triphenyl phosphonium bromide (MTPB), ethyl-triphenyl phosphonium bromide (ETPB), propyl-triphenyl phosphonium bromide (PTPB), and butyl-triphenyl phosphonium bromide (BTPB), combined with ethylene glycol (EG) were developed to synthesize four low-viscosity deep eutectic solvents (DESs). In this study, the effect of different substituents in DESs on low-concentration SO2 absorption was systematically studied at 30–70 °C. Experimental results show that the EG-MTPB DES has a higher SO2 absorption capacity and a lower viscosity than other DESs. The reason for the higher SO2 absorption capacity of EG-MTPB DES was described by viscosity experiments and quantum chemical calculations. It was shown that the strong polarization ability of the CH3 group promotes the absorption of SO2 by DESs. 1H NMR and FTIR results indicated that chemical interactions primarily exist between the S of SO2 and Br, and the O of SO2 and the H atom of EG form hydrogen bonds. The density functional theory (DFT) results also confirm that the charge of the Br atom migrated to the S atom. Also, thermostability and regeneration experiments showed that the EG-MTPB DES exhibits good stability and can thus be used for industrial flue gas desulfurization.