Highly efficient adsorption of congo red and methyl orange dyes using mesoporous α-Mn2O3 nanoparticles synthesized with Pyracantha angustofolia fruit extract

Abstract

Due to the many applications of manganese oxides in water treatment, this research aimed to synthesize α-Mn2O3 nanoparticles through a green method and investigate the dye adsorption capacity of them. The α-Mn2O3 nanoparticles were successfully synthesized using KMnO4 and aqueous extract of Pyracantha angustofolia fruits under hydrothermal conditions and calcination. The products were identified using Fourier transform infrared (FTIR), X-ray diffraction (XRD), Brunauer–Emmett–Teller (BET), and scanning electron microscopy (SEM) analyses. The adsorption capacity of methyl orange (MO) and Congo red (CR) dyes were evaluated at different concentrations (25, 50, and 75 ppm) using α-Mn2O3 nanoparticles. Results revealed the spherical and porous structure of α-Mn2O3 nanoparticles with a specific surface area of 21.7 m2.g-1. Dye removal significantly increased with pH decrement. The adsorption capacity for MO and CR was 73.07 and 70.70 mg.g−1, respectively. The adsorption data of both dyes followed a pseudo-second-order kinetic model. The best fitted models for MO and CR adsorption were the Langmuir isotherm and the Dubinin–Radushkevich, respectively. In addition, a possible adsorption mechanism was proposed for both dyes. The findings showed that α-Mn2O3 nanoparticles are very efficient adsorbents for removing anionic dyes.