Highly effectual photocatalytic degradation of tartrazine by using Ag nanoparticles decorated on Zn-Cu-Cr layered double hydroxide@ 2D graphitic carbon nitride (C3N5).

Abstract

Pollution of water resources is one of the main concerns of many countries. This issue originates from the entry of diverse pollutants, including dye compounds, into water sources. In this work, ternary Zn-Cu-Cr layered double hydroxides (LDH) supported on graphitic carbon nitride (g-C3N5) decorated by silver nanoparticles (C3N5-LDH-Ag) was first prepared. Application of various characterization techniques such as SEM, XRD, and FT-IR revealed that the synthesized nanocomposite was composed of Zn-Cu-Cr LDH nanoparticles, g-C3N5 nanosheets, and Ag nanoparticles. The prepared nanomaterials were employed for the photodegradation of tartrazine in aqueous solutions. It was found that the C3N5-LDH-Ag catalyst outperformed their pure g-C3N5, Zn-Cu-Cr LDH, and C3N5-LDH composite in photocatalytic degradation of tartrazine under visible light irradiation. Tartrazine (20mg/L) can be entirely removed by 0.25g/L C3N5-LDH-Ag photocatalyst under 1h visible light irradiation (200W) at pH 6 with a rapid degradation rate constant (k) that is 4.4, 3.9, and 2.6 times higher than that of pure C3N5, Zn-Cu-Cr LDH, and C3N5-LDH component, respectively. The formation of hydroxyl radicals on the surface of C3N5-LDH-Ag as the main active species was approved by the capturing experiment. The finding results approved the stability and reusability of C3N5-LDH-Ag in four photocatalytic degradation cycles. In general, our findings revealed that the synthesized nanocomposite could be employed as an efficient photocatalyst in environmental remediation.