Abstract
First planar chiral phosphapalladacycle was prepared in diastereomerically pure state via direct cyclopalladation of the di- tert-butyl-1-ferrocenylethylphosphine. The palladacycle structure was confirmed by 1 H NMR spectra; relative configuration of central and planar chirality was determined by an X-ray diffraction study of the triphenylphosphine adduct.
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