Abstract
Polymer electrolyte membranes comprising poly(vinylidene fluoride)−hexafluoropropene (PVdF−HFP) copolymer plasticized with a solution of LiSO3CF3, LiN(SO2CF3)2, or LiPF6 in oligomeric poly(ethylene glycol) dimethyl ethers (PEGDME, Mw = 250, 400, and 500) were prepared by hot-melt-rolling or solvent-casting techniques. Since the electrolytes containing PEGDME400 and PEGDME500 are “dry” with essentially no volatile components up to 150 °C, we have dubbed them PEO-like. Their thermal stability, mechanical strength, conductivity, electrochemical stability window, and Li/electrolyte interface stability were characterized. Plasticizing PVdF−HFP with the PEGDME/LiX solutions disordered the polymer structure leading to polymer electrolytes having lower crystallinity than the polymer host itself. The mechanical strength of the electrolyte membranes varied depending on the PVdF content. Tensile strength (stress) as high as 420 psi at an elongation-at-break value (strain) of 75% was observed. The conductivities of t...
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