High value utilization of waste peanut shell: Prepared novel shape stable composite phase change materials with high thermal conductivity

Abstract

To address the leakage and low thermal conductivity issues of phase change materials (PCMs), this study aims to prepare high thermal conductivity shape stable composite phase change materials (sscPCMs) using waste peanut shell. Employing pyrolysis technology, waste peanut shell has been successfully converted into high-performance framework materials. In addition, it also compared the thermal energy storage performance of shape stable composite stearic acid/peanut shell biochar (ss-cSA/PSC) with that of shape stable composite stearic acid/peanut shell (ss-cSA/PS). Excitingly, the thermal energy storage performance of ss-cSA/PSC has been significantly improved. Specifically, the thermal conductivity of ss-cSA/PSC reached 0.527 W/(m·K), which is 3.2 times higher than that of pure SA and 2.4 times higher than that of ss-cSA/PS. In addition, the phase change latent heat of ss-cSA/PSC can reach 70.59 J/g, which is 27.2% higher than that of ss-cSA/PS. The high thermal conductivity and phase change latent heat highlighted its significant superiority in the field of thermal energy storage. Furthermore, ss-cSA/PS and ss-cSA/PSC have been characterized by SEM, FTIR, XRD, and TGA. The results indicated that both two kinds of sscPCMs have excellent chemical compatibility, thermal reliability, and thermal stability. In summary, PSC is an economical, environmentally friendly, and sustainable framework material which used to prevent the leakage of PCMs and improve the thermal performance.