Abstract
In this paper, a series of terminal alloys were first prepared, undergoing microstructure and composition characterizations through a combination of X-ray diffraction (XRD), scanning electron microscopy (SEM), and electron probe microanalysis (EPMA) techniques. Subsequent diffusion couple experiments were conducted to acquire initial concentration profiles in fcc Co-Mn-Fe and Co-Mn-Ni alloys. By leveraging experimental composition profiles from 12 groups of diffusion couples measured using EPMA, alongside the reported thermodynamic data, atomic mobility parameters within the fcc phase of the two ternary systems were accurately determined using HitDIC software. Employing the resulting kinetic databases, a comprehensive set of simulated data, including composition profiles and diffusion paths, was generated for all diffusion couples, demonstrating strong alignment with corresponding experimental results. Moreover, interdiffusivities spanning a wider composition range within the fcc phase of Co-Mn-Fe and Co-Mn-Ni systems were computed at different temperatures, shedding light on the diffusion behavior of alloy components in response to temperature and concentration fluctuations. Finally, drawing from the reported thermodynamic data and the currently matched atomic mobility parameters, overviews of the intricate relationships among diffusion-related properties and configurational entropy indicate that the endeavor to develop comprehensive thermodynamic and kinetic databases is essential for tailoring High-Entropy Alloys.
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